Alamo and National are both serviced by Europcar in Ibiza so you use the Europcar desk and get Europcar cars. They are on-airport with access to the desk where you pick up keys in the baggage hall (airside of Customs). So you can have your keys before you get your bag off the carousel if there's no queue.
Cars are in the multi-storey car park opposite the terminal building (3 minute walk and open 24 hours for return). You can drop the key off in the terminal out of hours too if they have gone when you bring the car back. But it's always best to have the car signed off as in good nick and full (don't forget !) if you can otherwise excess is very high and you can find your card charged after returning home with no chance to argue the toss.
Alamo/Europcar are fine, as big car hire companies go, and way more convenient than the minibus thing you have to do with BK etc.
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